In MySql there is no UniqueIdentifier data-type. But you can still use it by creating a field of type CHAR(38) as length of UniqueIdentifier is 38 characters.
CREATE TABLE `sample` (
`Uid` char(38) NOT NULL,
PRIMARY KEY (`Uid`)
) ENGINE=InnoDB DEFAULT CHARSET=utf8;
Then in order to get random UniqueIdentifier value. You can make use of UUID() function of MySql which is similar to NEWID() of Sql Server.
INSERT INTO Sample(UId)
VALUES(UUID());
SELECT * FROM Sample;
Screenshot