ramco1917 says:
I want to add 1 Hr to Vtime and store in another variable say toTime.
To add 1 Hour you need to use AddHours method.
Then convert to time to DateTime and use the from and to time in the linq where clause.
Refer below example.
HTML
<asp:GridView ID="gvEmployees" runat="server" >
</asp:GridView>
Code
C#
protected void Page_Load(object sender, EventArgs e)
{
    if (!this.IsPostBack)
    {
        this.BindGridView();
    }
}
private void BindGridView()
{
    string mDate = "2022-07-18";
    string mTime = "10:25";
    int id = 1;
    string vDate = Convert.ToDateTime(mDate).ToString("dd-MM-yyyy");
    DateTime vTime = Convert.ToDateTime(mTime);
    DateTime toTime = Convert.ToDateTime(mTime).AddHours(1);
    using (NORTHWINDEntities entities = new NORTHWINDEntities())
    {
        var results = (from emp in entities.Employees
                        where emp.EmployeeID == id && (emp.BirthDate >= vTime && emp.BirthDate <= toTime)
                        select emp);
        gvEmployees.DataSource = results.ToList();
        gvEmployees.DataBind();
    }
}
VB.Net
Protected Sub Page_Load(ByVal sender As Object, ByVal e As EventArgs) Handles Me.Load
    If Not Me.IsPostBack Then
        Me.BindGridView()
    End If
End Sub
Private Sub BindGridView()
    Dim mDate As String = "2022-07-18"
    Dim mTime As String = "10:25"
    Dim id As Integer = 1
    Dim vDate As String = Convert.ToDateTime(mDate).ToString("dd-MM-yyyy")
    Dim vTime As DateTime = Convert.ToDateTime(mTime)
    Dim toTime As DateTime = Convert.ToDateTime(mTime).AddHours(1)
    Using entities As NORTHWINDEntities = New NORTHWINDEntities()
        Dim results = (From emp In entities.Employees
                        Where emp.EmployeeID = id AndAlso (emp.BirthDate >= vTime AndAlso emp.BirthDate <= toTime)
                        Select emp)
        gvEmployees.DataSource = results.ToList()
        gvEmployees.DataBind()
    End Using
End Sub
Screenshot
